Here we demonstrate a strategy to overcome this hurdle by avoiding the gaseous or liquid phase and directly converting glass into a single crystal.
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While the former has a tendency to crystallise, the latter has a normal (single) glass transition. Similarly, monomeric titanium 2-ethylhexanoate also has a single glass transition. Thus, the unusual double
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All the free-energy profiles show the simple double-well shape, whose two minima with low and high Q6v correspond to the liquid and crystal phases, respectively.
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On supercooling a liquid, the viscosity rises rapidly until at the glass transition it vitrifies into an amorphous solid accompanied by a steep drop in the heat capacity. Therefore, a pure...
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The ability to fabricate patterned single-crystal architecture on a glass surface is demonstrated, providing a new class of micro-structured substrate for low cost epitaxial growth,
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Here we show that homogeneous (pure) titanium alkoxide liquids exhibit two calorimetric glass transitions of comparable magnitude: that is, a comparable change in heat capacity.
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ABSTRACT: On supercooling a liquid, the viscosity rises rapidly until at the glass transition it vitrifies into an amorphous solid accompanied by a steep drop in the heat capacity.
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The present phase-separated MGs show double glass transition, crystallization and melting events. Our studies could render them useful for studying the glass transition and relaxation
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We extend the replica liquid theory in order to describe the multiple glass transitions of binary mixtures with large size disparities, by taking into account the two-step replica symmetry
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